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Though alkali metal NacNac (β-diketiminate) complexes have been utilised in synthesis as NacNac-transfer agents, studies of them in their own right with small molecules are exceptionally rare. Here, the lithium compound of the common 2,6-diisopropylphenyl-β-methyldiketiminate [NacNac(Dipp, Me)] ligand is investigated with carbon dioxide and isocyanates. In all four cases reaction occurs at the backbone γ-C atom of the NacNac ligand, which redistributes electronically into a diimine. Insertion of CO 2 gives an eight-atom carboxylate (Li 2O 4C 2) ring at the γ-C site in a dimer. Insertion of tBuNCO gives a secondary amide at the γ-C site in a monomer with TMEDA chelating lithium. Double insertion of tBuNCO and (adventitious) oxygen gives a dimer with a (LiO) 2 central core involving the latter source. Insertion of less bulky (iPrNCO) gives a dimer with dimerisation through the C=O bonds of the emergent secondary amide function.
- carbon dioxide fixation
- x-ray diffraction
FingerprintDive into the research topics of 'Backbone reactivity of lithium β-Diketiminate (NacNac) complexes with CO <sub>2</sub>, tBuNCO and iPrNCO'. Together they form a unique fingerprint.
- 2 Finished
1/10/16 → 23/06/20
Project: Research Studentship - Internally Allocated
Data for "Backbone reactivity of lithium β-diketiminate (NacNac) complexes with CO2, t-BuNCO and i-PrNCO"