@article{36a19a6cf3bf4600ade8b203f5602547,
title = "Development of chiral heteroleptic magnesium amides; asymmetric deprotonations mediated by six-membered metallocyclic amidomagnesium naphtholates",
abstract = "A series of enantioenriched six-membered metallocyclic amidomagnesium naphtholates were prepared and used to probe the structure-reactivity/selectivity relationships of heteroleptic magnesium base complexes within asymmetric deprotonation reactions. An effective complex was identified and applied within enantioselective enolisation processes, delivering good levels of enantioselectivity and also revealing key structural requirements for achieving such selectivity.",
keywords = "enantioselective deprotonation, heteroleptic magnesium bases, enolate, asymmetric synthesis, amidonaphtholate",
author = "Carswell, {Emma L.} and Kerr, {William J} and Duncan McArthur and Marek Pazicky and Allan Watson",
note = ". Notice: This is the author's version of a work that was accepted for publication in Tetrahedron. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Tetrahedron, Vol.70, No.40, 2014, DOI: 10.1016/j.tet.2014.06.052",
year = "2014",
month = oct,
day = "7",
doi = "10.1016/j.tet.2014.06.052",
language = "English",
volume = "70",
pages = "7344--7349",
journal = "Tetrahedron",
issn = "0040-4020",
number = "40",
}