Different sites of insertion in the reaction of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] (R=H or Me): N-H vs. Re-N

E Hevia, J Perez, V Riera, D Miguel

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The reactions of isocyanates with [Re(N(R)Ar)(CO)(3)(bipy)] complexes lead to R NCO insertion into the Re-N bond (for R = Me) or the N-H bond (R = H).

Original languageEnglish
Pages (from-to)1814-1815
Number of pages2
JournalChemical Communications
Issue number17
Publication statusPublished - 2002


  • aryloxide complexes
  • oxygen bonds
  • rhenium
  • amido
  • alkoxide
  • metals

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