Ferrocene derivatives. 23. Isocyanoferrocene and isothiocyanatoferrocene

Graham R. Knox; Peter L. Pauson; Debra Willison; Eva Solcaniova; Stefan Toma

doi:10.1021/om00116a002

Ferrocene derivatives. 23. Isocyanoferrocene and isothiocyanatoferrocene

Graham R. Knox, Peter L. Pauson, Debra Willison, Eva Solcaniova, Stefan Toma

Pure And Applied Chemistry

Research output: Contribution to journal › Article › peer-review

53 Citations (Scopus)

Abstract

Aminoferrocene has been converted into formamidoferrocene, which exists in solution as an equilibrium mixture of two rotational isomers, a monometic cis form and a dimeric (or oligomeric) trans form. Variable-temperature 2H and 13C1H NMR spectra have been used to measure AG for the hindered internal rotation about the C-N bond. Dehydration of formamidoferrocene yields isocyanoferrocene, which has been characterized by complex formation with iron and molybdenum carbonyls. A high-yield conversion of aminoferrocene into isothiocyanatoferrocene is described.

Original language	English
Pages (from-to)	301-306
Number of pages	6
Journal	Organometallics
Volume	9
Issue number	2
DOIs	https://doi.org/10.1021/om00116a002
Publication status	Published - 1 Feb 1990

Keywords

aminoferrocene
formamidoferrocene
isocyanoferrocene
isothiocyanatoferrocene

Access to Document

10.1021/om00116a002

Cite this

@article{f374e81c59244db8bfdc80712876cbbc,

title = "Ferrocene derivatives. 23. Isocyanoferrocene and isothiocyanatoferrocene",

abstract = "Aminoferrocene has been converted into formamidoferrocene, which exists in solution as an equilibrium mixture of two rotational isomers, a monometic cis form and a dimeric (or oligomeric) trans form. Variable-temperature 2H and 13C1H NMR spectra have been used to measure AG for the hindered internal rotation about the C-N bond. Dehydration of formamidoferrocene yields isocyanoferrocene, which has been characterized by complex formation with iron and molybdenum carbonyls. A high-yield conversion of aminoferrocene into isothiocyanatoferrocene is described.",

keywords = "aminoferrocene, formamidoferrocene, isocyanoferrocene, isothiocyanatoferrocene",

author = "Knox, {Graham R.} and Pauson, {Peter L.} and Debra Willison and Eva Solcaniova and Stefan Toma",

year = "1990",

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doi = "10.1021/om00116a002",

language = "English",

volume = "9",

pages = "301--306",

journal = "Organometallics",

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TY - JOUR

T1 - Ferrocene derivatives. 23. Isocyanoferrocene and isothiocyanatoferrocene

AU - Knox, Graham R.

AU - Pauson, Peter L.

AU - Willison, Debra

AU - Solcaniova, Eva

AU - Toma, Stefan

PY - 1990/2/1

Y1 - 1990/2/1

N2 - Aminoferrocene has been converted into formamidoferrocene, which exists in solution as an equilibrium mixture of two rotational isomers, a monometic cis form and a dimeric (or oligomeric) trans form. Variable-temperature 2H and 13C1H NMR spectra have been used to measure AG for the hindered internal rotation about the C-N bond. Dehydration of formamidoferrocene yields isocyanoferrocene, which has been characterized by complex formation with iron and molybdenum carbonyls. A high-yield conversion of aminoferrocene into isothiocyanatoferrocene is described.

AB - Aminoferrocene has been converted into formamidoferrocene, which exists in solution as an equilibrium mixture of two rotational isomers, a monometic cis form and a dimeric (or oligomeric) trans form. Variable-temperature 2H and 13C1H NMR spectra have been used to measure AG for the hindered internal rotation about the C-N bond. Dehydration of formamidoferrocene yields isocyanoferrocene, which has been characterized by complex formation with iron and molybdenum carbonyls. A high-yield conversion of aminoferrocene into isothiocyanatoferrocene is described.

KW - aminoferrocene

KW - formamidoferrocene

KW - isocyanoferrocene

KW - isothiocyanatoferrocene

U2 - 10.1021/om00116a002

DO - 10.1021/om00116a002

M3 - Article

VL - 9

SP - 301

EP - 306

JO - Organometallics

JF - Organometallics

SN - 0276-7333

IS - 2

ER -