Study of superhydrophobic electrosprayed catalyst layers using a localized reference electrode technique

A. M. Chaparro, P. Ferreira-Aparicio, M. A. Folgado, E. Brightman, G. Hinds

Research output: Contribution to journalArticlepeer-review

19 Citations (Scopus)


The performance of electrosprayed cathode catalyst layers in a polymer electrolyte membrane fuel cell (PEMFC) is studied using a localized reference electrode technique. Single cells with an electrosprayed cathode catalyst layer show an increase of >20% in maximum power density under standard testing conditions, compared with identical cells assembled with a conventional, state-of-the-art, gas diffusion cathode. When operated at high current density (1.2 A cm−2) the electrosprayed catalyst layers show more homogeneous distribution of the localized cathode potential, with a standard deviation from inlet to outlet of <50 mV, compared with 79 mV for the conventional gas diffusion cathode. Higher performance and homogeneity of cell response is attributed to the superhydrophobic nature of the macroporous electrosprayed catalyst layer structure, which enhances the rate of expulsion of liquid water from the cathode. On the other hand, at low current densities (<0.5 A cm−2), the electrosprayed layers exhibit more heterogeneous distribution of cathode potential than the conventional cathodes; this behavior is attributed to less favorable kinetics for oxygen reduction in very hydrophobic catalyst layers. The optimum performance may be obtained with electrosprayed catalyst layers employing a high Pt/C catalyst ratio.

Original languageEnglish
Pages (from-to)609-619
Number of pages11
JournalJournal of Power Sources
Early online date23 Jun 2016
Publication statusPublished - 1 Sep 2016


  • catalyst layer
  • electrospray
  • fuel cell
  • localized reference electrode


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